{2,6-Bis[(2,6-diphenylphosphanyl)oxy]-4-fluorophenyl-κ3 P,C 1,P′}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathiazin-3-ido-κN)palladium(II)
نویسندگان
چکیده
The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L-Pd-L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd-N = 2.127 (2) Å] with a dihedral angle of 76.35 (6)° relative to the square plane. Relatively long phen-yl-acesulfamate C-H⋯O and phen-yl-fluorine C-H⋯F inter-actions consolidate the crystal packing.
منابع مشابه
trans-Bis(ethylenediamine-κ2 N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
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